Resonant multiphoton ionisation and third-harmonic generation in mercury vapour

Abstract
The interaction of intense dye laser radiation (up to about 100 GW cm-2) with Hg vapour in the pressure region of 1015 to 10-1 Torr leads to competition between multiphoton ionisation-dominant at low pressure-and third-harmonic generation ( approximately 1850AA) prevailing at high pressure. In particular, third-harmonic generation enhanced by a four-photon resonance is-to the authors' knowledge-reported for the first time.