Gas-Phase Electron Resonance Spectra of SF and SeF

15 March 1969

journal article
research article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 50 (6), 2726-2732
https://doi.org/10.1063/1.1671436

Abstract

The electron resonance spectra of the gaseous radicals SF and SeF have been detected and analyzed. The derivation of an effective Hamiltonian which operates in the rotational subspace of the ground vibronic state is described. Use of this Hamiltonian yields the rotational constants, the fine‐structure splittings, and the axial components of the ¹⁹F hyperfine interaction for both radicals.

Keywords

FINE STRUCTURE

This publication has 15 references indexed in Scilit:

Stark Effect in Gas-Phase Electron Resonance. The Dipole Moments of ClO, BrO, SH, and 1Δ SO
The Journal of Chemical Physics, 1967
Gas-Phase Electron Resonance Spectrum of ClO
The Journal of Chemical Physics, 1967
Gas-Phase Electron Resonance Spectra of Fluorine and Chlorine Atoms in Their Ground (P322) and Excited (2P½) Electronic States
The Journal of Chemical Physics, 1966
$L$ -Uncoupling Effects on the Electron-Paramagnetic-Resonance Spectra of $N^{14}$ $O^{16}$ and $N^{15}$ $O^{16}$
Physical Review B, 1966
Uncoupling Effects in the Microwave Spectrum of Nitric Oxide
Physical Review B, 1956
Theory of the Hyperfine Structure of the NO Molecule. II. Errata and Some Additional Discussion
Physical Review B, 1955
Theory of the Fine Structure of the Molecular Oxygen Ground State
Physical Review B, 1955
Theory of the Microwave Zeeman Effect in Atomic Oxygen
Physical Review B, 1953
The Coupling of Angular Momentum Vectors in Molecules
Reviews of Modern Physics, 1951
Relativistic Magnetic Moment of a Charged Particle
Physical Review B, 1940

Cited by 73 articles