Resonances in molecular photoionization. II. Autoionization effects in the NO molecule
- 1 July 1987
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 87 (1), 331-338
- https://doi.org/10.1063/1.453632
Abstract
Near-threshold autoionization features in the photoionization spectroscopy of nitric oxide are studied by the use of the Feshbach projection-operator formalism of scattering theory. The complex autoionization structure in the photoionization spectrum of NO in the wavelength region of 1140–950 Å is described by assuming one valence state interacting with the ionization continuum and the converging Rydberg series. The strong non-Condon effects observed in the photoelectron spectra of this molecule are also discussed.Keywords
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