Electronic Raman Spectra. III. Absolute Cross Sections for Electronic Raman and Rayleigh Scattering
- 5 April 1968
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 168 (1), 75-78
- https://doi.org/10.1103/physrev.168.75
Abstract
Absolute cross sections for Rayleigh and electronic Raman scattering of trivalent rare-earth ions have been calculated. A comparison with the experimental cross section for benzene reveals that both the Rayleigh and Raman scattering for the lanthanides is weaker by more than two orders of magnitude. The Rayleigh-to-Raman ratio is shown to be a rapidly fluctuating function of the electronic structure of the lanthanide ions.Keywords
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