Low‐Melting, Low‐Viscous, Hydrophobic Ionic Liquids: 1‐Alkyl(Alkyl Ether)‐3‐methylimidazolium Perfluoroalkyltrifluoroborate
- 1 December 2004
- journal article
- research article
- Published by Wiley in Chemistry – A European Journal
- Vol. 10 (24), 6581-6591
- https://doi.org/10.1002/chem.200400533
Abstract
A series of twenty two hydrophobic ionic liquids, 1-alkyl(alkyl ether)-3-methylimidazolium ([Cmmim]+ or [CmOnmim]+; where Cm is 1-alkyl, Cm=nCmH2m+1, m=1–4 and 6; CmOn is 1-alkyl ether, C2O1=CH3OCH2, C3O1=CH3OCH2CH2, and C5O2=CH3(OCH2CH2)2) perfluoroalkyltrifluoroborate ([RFBF3]−, RF=CF3, C2F5, nC3F7, nC4F9), have been prepared and characterized. Some of the important physicochemical properties of these salts including melting point, glass transition, viscosity, density, ionic conductivity, thermal and electrochemical stability, have been determined and were compared with those of the reported [BF4]−-based ones. The influence of the structure variation in the imidazolium cation and the perfluoroalkyltrifluoroborate ([RFBF3]−) anion on the above physicochemical properties was discussed. The key features of these new salts are their low melting points (−42 to 35 °C) or extremely low glass transition (between −87 and −117 °C) without melting, and considerably low viscosities (26–77 cP at 25 °C).Keywords
This publication has 71 references indexed in Scilit:
- Halofluorination of alkenes with ionic liquid EMIMF(HF)2.3Journal of Fluorine Chemistry, 2004
- New hydrophobic ionic liquids based on perfluoroalkyltrifluoroborate anionsJournal of Fluorine Chemistry, 2004
- Physical and electrochemical properties of 1-alkyl-3-methylimidazolium tetrafluoroborate for electrolyteJournal of Fluorine Chemistry, 2003
- Physicochemical Properties of 1,3-Dialkylimidazolium Fluorohydrogenate Room-Temperature Molten SaltsJournal of the Electrochemical Society, 2003
- (POLYFLUOROORGANO)HALOBORANES AND (POLYFLUOROORGANO)FLUOROBORATE SALTS: PREPARATION, NMR SPECTRA AND REACTIVITYMain Group Metal Chemistry, 2002
- A Preparative Method for Perfluoroalkyltrifluoroborates and PerfluoroalkyldifluoroboranesZeitschrift für anorganische und allgemeine Chemie, 2001
- Room temperature ionic liquids of alkylimidazolium cations and fluoroanionsJournal of Fluorine Chemistry, 2000
- Thermal properties of imidazolium ionic liquidsThermochimica Acta, 2000
- Ionic LiquidsClean Technologies and Environmental Policy, 1999
- Acidic 1-ethyl-3-methylimidazolium fluoride: a new room temperature ionic liquidJournal of Fluorine Chemistry, 1999