Heterodyne-Detected Fifth-Order Nonresonant Raman Scattering from Room Temperature
- 30 April 2002
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 88 (20), 207402
- https://doi.org/10.1103/physrevlett.88.207402
Abstract
Actively phase-locked heterodyne-detected fifth-order nonresonant Raman scattering from room temperature has been measured. The experimental signals have similar magnitudes, shapes, and sign changes as calculated responses obtained via molecular dynamics simulations [S. Saito and I. Ohmine, Phys. Rev. Lett. 88, 207401 (2002)]. The measured signals contain sign changes that appear to be associated with the coupling of rotational motions both to each other and to translational motions.
Keywords
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