Infrared Spectrum of the Dimethylnitrilium Ion
- 1 April 1959
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 30 (4), 895-898
- https://doi.org/10.1063/1.1730122
Abstract
The infrared spectrum of the dimethylnitrilium ion is presented and discussed. Thirteen of the fifteen infrared active fundamentals expected for the ion on the basis of a C3v′ structure are assigned, and the frequencies of the two remaining fundamentals are estimated from observed combination bands. A calculation of the skeletal bond stretching and bending force constants is given.Keywords
This publication has 5 references indexed in Scilit:
- Über Nitriliumsalze, I. Mitteil.European Journal of Inorganic Chemistry, 1956
- Untersuchungen in der Reihe der Nitrilium‐Salze 5. Mitteilung über OniumsalzeEuropean Journal of Organic Chemistry, 1955
- Internal rotation in dimethyl acetyleneProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1954
- A Ratio-Recording Double-Beam Infra-Red Spectrophotometer with Automatic Slit-Control*†Journal of the Optical Society of America, 1950
- Infra-Red and Raman Spectra of Polyatomic Molecules IX. Dimethyl Acetylene, C4H6The Journal of Chemical Physics, 1939