Metal‐Catalyzed Enantioselective Allylation in Asymmetric Synthesis
Top Cited Papers
- 19 December 2007
- journal article
- review article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 47 (2), 258-297
- https://doi.org/10.1002/anie.200605113
Abstract
Metal-catalyzed enantioselective allylation, which involves the substitution of allylic metal intermediates with a diverse range of different nucleophiles or SN2′-type allylic substitution, leads to the formation of CH, C, O, N, S, and other bonds with very high levels of asymmetric induction. The reaction may tolerate a broad range of functional groups and has been applied successfully to the synthesis of many natural products and new chiral compounds.Keywords
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