Some unusual bridged sulphido-derivatives of iron carbonyl

1 January 1970

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications

No. 5,p. 288
https://doi.org/10.1039/c29700000288

Abstract

The reactions of Fe₃(CO)₁₂ with the secondary and tertiary alkyl thiols RSH (R = Prⁱ, Bu^s, and Bu^t) in refluxing benzene afford the novel bridged sulphido-derivatives Fe₃(CO)₉(H)(SR), Fe₃(CO)₉(SBu^t)₂, and Fe₄(CO)₁₂(SBu^t)₂(S).

Keywords

IRON

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