Pd(II)-Catalyzed Amination of C−H Bonds Using Single-Electron or Two-electron Oxidants
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- 16 July 2009
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 131 (31), 10806-10807
- https://doi.org/10.1021/ja904709b
Abstract
Pd(II)-catalyzed intramolecular amination of arenes is developed using either a one- or two-electron oxidant. The reaction protocol tolerates a wide range of deactivating groups including acetyl, cyano, and nitro groups. This catalytic reaction allows expedient syntheses of broadly useful substituted indolines or indoles.Keywords
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