Anomalous Densities in Liquid Crystalline bis-(4-n-alkoxybenzal)-1, 4-phenylenediamines

Abstract
Recently Arora, Taylor, Fergason and Saupe(1,2) investigated the homologous series of the bis-(4-n-alkoxybenzal)-1, 4-phenylenediamines. In contradiction to Gray,(3) who found in this series only one nematic and one smectic modification, they observed besides one nematic modification a number of smectic phases, up to five for several substances. The greatest number of phase transitions were found in the case of the heptyloxy- up to the decyloxy-derivatives.