Measurements of CH4and N2O fluxes at the landscape scale using micrometeorological methods

Abstract
Flux gradient, eddy covariance and relaxed eddy accumulation methods were applied to measure CH4and N2O emissions from peatlands and arable land respectively. Measurements of N2O emission by eddy covariance using tunable diode laser spectroscopy provided fluxes ranging from 2 to 60 µ mol N2O m-2h-1with a mean value of 22 µ mol N2O m-2h-1from 320 h of continuous measurements. Fluxes of CH4measured above peatland in Caithness (U.K.) during May and June 1993 by eddy covariance and relaxed eddy accumulation methods were in the range 70 to 120 µ mol CH4m-2h-1with means of 14.7 µ mol CH4m-2h-1and 22.7 µ mol CH4m-2h-1respectively. Emissions of CH4from peatland changed with water table depth and soil temperature; increasing from 25 |Amol CH4m-2h-1at 5% pool area to 50 p.mol CH4m-2h-1with 30% within the flux footprint occupied by pools. A temperature response of 4.9 (xmol CH4m-2h-1°C-1in the range 6-12 °C was also observed. The close similarity in average CH4emission fluxes reported for wetlands in Caithness, Hudson Bay and Alaska in the range 11 to 40 jamol CH4m-2h-1suggests that earlier estimates of CH4emission from high latitude wetlands were too large or that the area of high latitudes contributing to CH4emission has been seriously underestimated.