Alkenyl Stannane-Allylic Halide Macrocyclisations. An Approach to Amphidinolide A and Related Polyolefin Macrolide Systems

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Abstract
A synthetic approach to polyolefin macrolides based on intramolecular Stille-type coupling reactions between alkenyl stannanes and allylic chlorides is described, e.g. 8 → 10, 11 → 12.