A key step in the formation of acrylic acid from CO2and ethylene: the transformation of a nickelalactone into a nickel-acrylate complex
- 9 May 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2510-2512
- https://doi.org/10.1039/b603540j
Abstract
The reaction of a nickelalactone with dppm, resulting in the formation of a stable binuclear Ni(I) complex with an acrylate, a Ph2P− and a dppm bridge, models a key step in the formation of acrylic acid from CO2 and ethylene.Keywords
This publication has 17 references indexed in Scilit:
- Organometallic Nickelamacrocycles of the Type [(R2R‘P)Ni(C2H4COO)]n: Synthesis and Self-Assembly to Form Different Molecular Architectures Tuned by the PhosphineOrganometallics, 2004
- Acrylate Formation via Metal-Assisted C−C Coupling between CO2 and C2H4: Reaction Mechanism as Revealed from Density Functional CalculationsJournal of the American Chemical Society, 2003
- Synthesis, characterization and reactivity of [Rh(bpy)(C2H4)Cl]. A study on the reaction with C1 molecules (CH2O, CO2) and NaBPh4Journal of Organometallic Chemistry, 1993
- Bis(ethylene) complexes of molybdenum and tungsten and their reactivity toward carbon dioxide. New examples of acrylate formation by coupling of ethylene and carbon dioxideOrganometallics, 1993
- Formation of carboxylate complexes from the reactions of carbon dioxide with ethylene complexes of molybdenum and tungsten. X-ray and neutron diffraction studiesOrganometallics, 1989
- Zur Synthese und Charakterisierung von N,N′‐Tetramethylethylendiamin‐nickelacyclopropionatZeitschrift für anorganische und allgemeine Chemie, 1989
- CC‐Linkages of Ethene with CO2 on an Iron(0) Complex—Synthesis and Crystal Structure Analysis of [(PEt3)2Fe(C2H4)2]Angewandte Chemie International Edition in English, 1987
- Formation of acrylic acid derivatives from the reaction of carbon dioxide with ethylene complexes of molybdenum and tungstenJournal of the American Chemical Society, 1985
- Titanacycles derived from reductive coupling of nitriles, alkynes, acetaldehyde, and carbon dioxide with bis(pentamethylcyclopentadienyl)(ethylene)titanium(II)Organometallics, 1985
- Zur Kenntnis der Chemie der Metallcarbonyle und der Cyanokomplexe in flüssigem Ammoniak, XIII. Zur Kenntnis der Reaktionsweisen der Cyanometallate(O) K6[Cr(CN)6] und K4[Ni(CN)4]Zeitschrift für anorganische und allgemeine Chemie, 1965