Synthesis of 12‐Methyl‐13‐tridecanolide
- 12 August 1987
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 70 (5), 1389-1392
- https://doi.org/10.1002/hlca.19870700519
Abstract
The title compound was prepared from 2‐nitrocyclodecanone (2). Compound 2 was treated with 2‐methylpro‐penal to give the Michael‐addition product 3 which was reduced to the alcohol 5 and the latter ring‐enlarged with Bu4NF to 12‐methyl‐10‐nitro‐13‐tridecanolide (6) followed by reductive elimination of the NO2 group by Bu3SnH.This publication has 9 references indexed in Scilit:
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