Photoinduced Desorption of Sulfur from Gold Nanoparticles Loaded on Metal Oxide Surfaces

Abstract

We now report photoinduced sulfur desorption from the surfaces of Au nanoparticles loaded on metal oxides. This reaction occurs in water at ordinary temperature and pressure. Nanometer-sized Au particles have been formed on the surfaces of various metal oxides by deposition−precipitation (Au/oxides). Elemental sulfur (S₈) is selectively adsorbed on the Au nanoparticle surfaces of Au/oxides in an atomic state at a coverage of (θ) ≤ 1/3 and in both atomic and molecular states at θ > 1/3. Irradiation (λ_ex > 300 nm) of the sulfur adsorbed Au/anatase TiO₂ in water has led to reductive desorption of the sulfurs at room temperature. Electrochemical measurements using Au/oxides indicate that the driving force for this reaction is the photoinduced upward shift of Fermi energy of the metal oxide-supported Au nanoprticles. This study will open up a novel and wide application of heterogeneous photocatalysis for thermal catalysts.