Bridged Triarylamines: A New Class of Heterohelicenes
- 13 March 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 68 (16), 6071-6078
- https://doi.org/10.1021/jo026883p
Abstract
A series of bridged triarylamines, which constitute a new class of heterohelicenes, have been synthesized using a simple three-step procedure. These compounds are shown to be highly luminescent chromophores and are capable of being oxidized. The solid-state structures of these helicenes show a tendency for π-stacking interactions into an overall zigzag motif.Keywords
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