Detailed phytochemical investigation of ethyl acetate extract of K. pinnata revealed the presence of glycosides A, B and C. Glycoside A is still to be worked out. Glycoside B has been characterized as quercetin 3–diarabinoside, not reported previously in the literature. While glycoside C has been identified as kaempferol 3–glucoside, isolated for the first time in Kalanchoe species.