Thermodynamical Liquid-Glass Transition in a Lennard-Jones Binary Mixture
- 10 January 2000
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 84 (2), 306-309
- https://doi.org/10.1103/physrevlett.84.306
Abstract
We use results derived in the framework of the replica approach to study the liquid-glass thermodynamic transition. The main results are derived without using replicas and applied to the study of the Lennard-Jones binary mixture introduced by Kob and Andersen. We find that there is a phase transition due to the entropy crisis. We compute both analytically and numerically the value of the phase transition point and the specific heat in the low temperature phase.
Keywords
All Related Versions
This publication has 21 references indexed in Scilit:
- Analytic Computation of the Instantaneous Normal Modes Spectrum in Low-Density LiquidsPhysical Review Letters, 1999
- Density functional theory and the asymptotic high density expansion of the free energy of classical solids and fluidsMolecular Physics, 1998
- Harmonic Dynamics in Supercooled Liquids: The Case of WaterPhysical Review Letters, 1997
- Structural Glass Transition and the Entropy of the Metastable StatesPhysical Review Letters, 1995
- Are disordered spin glass models relevant for the structural glass problem?Transport Theory and Statistical Physics, 1995
- A Topographic View of Supercooled Liquids and Glass FormationScience, 1995
- Formation of Glasses from Liquids and BiopolymersScience, 1995
- Scaling Behavior in the-Relaxation Regime of a Supercooled Lennard-Jones MixturePhysical Review Letters, 1994
- Relaxation processes in supercooled liquidsReports on Progress in Physics, 1992
- Hidden structure in liquidsPhysical Review A, 1982