Reactions of O Atoms with Isobutane
- 15 February 1963
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 38 (4), 950-958
- https://doi.org/10.1063/1.1733790
Abstract
The reaction of isobutane with oxygen atoms produced by a titration technique has been studied in the gas phase at 30°C. The experimental evidence leads to the conclusion that hydrogen abstraction by the oxygen atoms plays only a minor role and that the reaction products are formed in a more direct manner by the simultaneous replacement by an oxygen atom, of two groups on the parent hydrocarbon.Keywords
This publication has 17 references indexed in Scilit:
- Analysis of peroxides separation and identification by paper chromatographyAnalytica Chimica Acta, 1960
- ELECTROPHILIC CHARACTER OF OXYGEN ATOMSCanadian Journal of Chemistry, 1960
- ABSOLUTE RATE MEASUREMENTS OF O-ATOM REACTIONS WITH ETHYLENE AND WITH BUTANECanadian Journal of Chemistry, 1960
- The Thermochemistry And Reactivity Of Alkoxyl RadicalsChemical Reviews, 1959
- Relative Rates of Reactions of Oxygen Atoms with OlefinsThe Journal of Chemical Physics, 1959
- The air afterglow and its use in the study of some reactions of atomic oxygenProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1958
- MOLECULAR REARRANGEMENTS IN THE REACTIONS OF OXYGEN ATOMS WITH OLEFINSCanadian Journal of Chemistry, 1958
- Vibrationally Excited Ground-State Nitrogen in Active NitrogenThe Journal of Chemical Physics, 1958
- Rate Constants at Low Concentrations. III. Atomic Oxygen Reactions in the Photolysis of Nitrogen Dioxide at 3660 AThe Journal of Chemical Physics, 1957
- Decompositions of Di-t-alkyl Peroxides. IV. Decomposition of Pure Liquid PeroxideJournal of the American Chemical Society, 1950