Ionic conductivity in Li3N single crystals
- 15 June 1977
- journal article
- Published by AIP Publishing in Applied Physics Letters
- Vol. 30 (12), 621-623
- https://doi.org/10.1063/1.89283
Abstract
Lithium ionic conductivity of Czochralski‐grown Li3N single crystals using electrochemical transport measurements is reported. The highest Li ionic conductivity was found perpendicular to the hexagonal c axis, the anisotropy decreasing from two to one decade between 20 and 200 °C. Ambient Li ionic conductivity parallel to the Li2N planes of the layer structure was found to be σ=10−3 Ω−1 cm−1 with an activation energy of 0.25 eV. These values are comparable with the best data reported for Li β‐alumina single crystals.Keywords
This publication has 7 references indexed in Scilit:
- Re-evaluation of the lithium nitride structureJournal of the Less Common Metals, 1976
- Ionic conductivity of lithium phosphate-doped lithium orthosilicateMaterials Research Bulletin, 1976
- Ionic conductivity of alkali metal chloroaluminatesPhysics Letters A, 1976
- Flop-para critical field in diluted antiferromagnetPhysics Letters A, 1976
- Lithium nitride (Li3N): standard enthalpy of formation by solution calorimetryThe Journal of Chemical Thermodynamics, 1975
- Spektroskopische Untersuchungen in der Festkörperchemie / Spectroscopic Research in Solid-State ChemistryZeitschrift für Naturforschung B, 1970
- NMR Studies of 7Li in Polycrystalline Lithium NitrideThe Journal of Chemical Physics, 1966