Water and Ice
- 23 August 2002
- journal article
- editorial
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 297 (5585), 1288-1289
- https://doi.org/10.1126/science.297.5585.1288
Abstract
The water phase diagram is extraordinarily complex. In addition to numerous solid phases of ice, studies have pointed to the existence of distinct amorphous phases. It has even been proposed that there may be a liquid-liquid critical point, where two different liquid phases coexist. In his Perspective, Soper highlights the report by Tulk et al., whose results provide evidence against distinct amorphous phases. These phases were believed to be the low-temperature manifestations of the two liquid forms of water. The work raises doubts about the idea that there is a liquid-liquid phase separation in low-temperature water.Keywords
This publication has 7 references indexed in Scilit:
- Structural Studies of Several Distinct Metastable Forms of Amorphous IceScience, 2002
- A single-bond approach to orientation-dependent interactions and its implications for liquid waterThe Journal of Chemical Physics, 1999
- Phase behaviour of metastable waterNature, 1992
- Diffusion in supercooled water to 300 MPaPhysical Review Letters, 1987
- ‘Melting ice’ I at 77 K and 10 kbar: a new method of making amorphous solidsNature, 1984
- Stability-limit conjecture. An interpretation of the properties of waterThe Journal of Physical Chemistry, 1982
- Density, thermal expansivity, and compressibility of liquid water from 0.deg. to 150.deg.. Correlations and tables for atmospheric pressure and saturation reviewed and expressed on 1968 temperature scaleJournal of Chemical & Engineering Data, 1975