Co-ordination state of copper(II) ion in Cu(O2CMe)2–pyridine derivative–diluent mixtures; the steric effect of the amine ligand
- 1 January 1990
- journal article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 3,p. 733-736
- https://doi.org/10.1039/dt9900000733
Abstract
Electronic spectra (360–800 nm) and electrolytic conductivities have been measured for the Cu(O2CMe)2–L–chlorobenzene systems (L = 2-chloro-, 2-methyl-, 2-ethyl-, 2,4-dimethyl-, or 2,6-dimethyl-pyridine) and Kth for the equilibrium 2[Cu(O2CMe)2L2] [Cu2(O2CMe)4L2] + 2L calculated. The results are compared with those obtained for non-α-substituted pyridines as ligands. A strong steric effect on the co-ordination equilibria as well as on the stereochemistry and solvation of the mononuclear [Cu(O2CMe)2L2] complexes has been evidenced and discussed.Keywords
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