SULFONIUM SALT SOLVOLYSIS: PART V. MODEL SYSTEMS FOR BIOLOGICAL TRANSMETHYLATION
Open Access
- 1 January 1965
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 43 (1), 57-63
- https://doi.org/10.1139/v65-008
Abstract
The rates of solvolysis of a series of sulfonium salts which may be considered as models for the biologically important sulfonium salt, S-adenosylmethionine, are discussed in terms of a possible anchimeric role of the carboxyl group of methionine in transmethylation reactions.Keywords
This publication has 7 references indexed in Scilit:
- Solvents of Low Nucleophilicity. III. The Effect of Remote Substituents in the Addition of Trifluoroacetic Acid to Substituted AlkenesJournal of the American Chemical Society, 1963
- SULPHONIUM SALT SOLVOLYSIS: PART III. NUCLEOPHILIC ROLE OF ANIONS IN SOLVOLYSIS OF DIMETHYL-t-BUTYL SULPHONIUM SALTSCanadian Journal of Chemistry, 1962
- A CONTINUOUS FLOW COUNTING RADIOCHEMICAL TECHNIQUE FOR THE STUDY OF SOLUTION KINETICS1The Journal of Physical Chemistry, 1960
- REACTIONS OF ARYLSULPHONIC ESTERS: III. ON THE HYDROLYSIS OF METHYL p-METHYLBENZENESULPHONATECanadian Journal of Chemistry, 1955
- Synthesis and Properties of Derivatives of Spiro[4.4]nonane1Journal of the American Chemical Society, 1954
- Refractive Index-Temperature Data for Anhydrous Ethyl AlcoholAnalytical Chemistry, 1952
- The Role of Neighboring Groups in Replacement Reactions. V. The Effect of the Neighboring Acetoxy Group on the Course of the Replacement of the Tosylate Group of trans-2-Acetoxycyclohexyl p-Toluenesulfonate1Journal of the American Chemical Society, 1942