The correlation of theã,3A2state of CS2with states of linear CS2
- 1 January 1973
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 25 (1), 137-144
- https://doi.org/10.1080/00268977300100151
Abstract
It is shown from gas phase band intensity measurements that the ã - X system of CS2 is vibronically induced with a transition moment proportional to the second power of the bending normal coordinate of the linear ground state. Hence it is deduced that the ã, 3 A 2 state of bent CS2 is derived from the 2 u component of a 3Δ u state of linear CS2. This orbital nature of the ã state is also consistent with the observed Zeeman effect.Keywords
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