Quantum Statistical Mechanics of Isotope Effects
- 1 July 1961
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 35 (1), 35-40
- https://doi.org/10.1063/1.1731913
Abstract
Expansions in powers of Planck's constant are utilized in a discussion of isotope effects on the thermodynamic properties of fluid systems. Theoretical calculations of the differences in the equations of state of the hydrogen isotopes and of the helium isotopes are presented and comparison with experimental results are made. Agreement between theory and experiment is excellent.Keywords
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