Use of Trifluoromethanesulfonic Acid in Fischer Glycosylations
- 1 March 1988
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 7 (1), 263-269
- https://doi.org/10.1080/07328308808058919
Abstract
The Fischer glycosylation1 is one of the standard reactions in carbohydrate chemistry, in which a reducing sugar is reacted under acid catalysis with a simple alcohol to give a glycoside. Hydrochloric acid is the classical catalyst, but other proton, Lewis acid, or acid form ion echange resins have also been used. Now, the use of trifluoromethanesulfonic acid (triflic acid) as a catalyst is communicated.Keywords
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