Abstract
An extra electron in liquid argon does not form a localized state. The free‐ion yield in liquid argon is G(e)fi ≈ 5 , which indicates that all the ion–electron pairs formed during the x radiolysis of argon become free ions. The difference between the values of Gfi in neopentane (0.9) and n‐hexane (0.13) is due to the smaller efficiency of electron localization in the former than in the latter liquid. The efficiency of electron localization is a function of the geometry of the hydrocarbon molecule.