Radiation-Induced Electrical Conductance in the Liquids Argon, Neopentane, and n-Hexane: The Influence of Electron Localization Efficiency on the Free-Ion Yield
- 15 August 1969
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 51 (4), 1276-1279
- https://doi.org/10.1063/1.1672171
Abstract
An extra electron in liquid argon does not form a localized state. The free‐ion yield in liquid argon is , which indicates that all the ion–electron pairs formed during the x radiolysis of argon become free ions. The difference between the values of in neopentane (0.9) and n‐hexane (0.13) is due to the smaller efficiency of electron localization in the former than in the latter liquid. The efficiency of electron localization is a function of the geometry of the hydrocarbon molecule.
Keywords
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