Preparation and Characterization of New Room Temperature Ionic Liquids

Abstract

A new series [C_nO_mmim][X] of imidazolium cation‐based room temperature ionic liquids (RTILs), with ether and alcohol functional groups on the alkyl side‐chain has been prepared. Some physical properties of these RTILs were measured, namely solubility in common solvents, viscosity and density. The solubility of LiCl, HgCl₂ and LaCl₃ in room temperature ionic liquids was also determined. The features of the solid–liquid phase transition were analysed, namely the glass transition temperature and the heat capacity jump associated with the transition from the non‐equilibrium glass to the metastable supercooled liquid. These properties were compared with those reported for the 1‐n‐alkyl‐3‐methylimidazolium [C_nmim][X] series. While the density and solid–liquid phase transition properties are similar for both series, the new RTILs present a considerably lower viscosity and an increased ability to dissolve HgCl₂ and LaCl₃ (up to 16 times higher).