METALLO-ORGANIC COMPOUNDS CONTAINING METAL–NITROGEN BONDS: PART IV. SOME BIS-(PRIMARY AMINO)-TITANIUM COMPOUNDS
- 1 January 1963
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 41 (1), 134-138
- https://doi.org/10.1139/v63-017
Abstract
The aminolysis reactions involving primary amines with either Ti(NMe2)4 or Ti(NEt2)4 have been studied. The primary amines behave as bifunctional reactants, forming colored, insoluble, non-volatile bis-(primary amino)-titanium compounds Ti(NR)2 which (except for R = C6H5) are highly reactive towards water or alcohols. With n-butylamine, some soluble polymers of the general formula Tix(NBun)2x−2(NEt2)4 were isolated. With tert-butyl-amine the dimers Ti2(NBut)2(NMe2)4 and Ti2(NBut)2(NHBut)2(NMe2)2 were obtained. The structures of these polymeric metal–nitrogen compounds are discussed.Keywords
This publication has 2 references indexed in Scilit:
- 765. Metallo-organic compounds containing metal–nitrogen bonds. Part I. Some dialkylamino-derivatives of titanium and zirconiumJournal of the Chemical Society, 1960
- 2. The effect of solvents on the molecular complexities of tantalum n-alkoxidesJournal of the Chemical Society, 1956