Multiphoton spectroscopy of X–NO (X=Kr, Xe, CH4) van der Waals molecules
- 15 March 1987
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 86 (6), 3166-3171
- https://doi.org/10.1063/1.452027
Abstract
The vibronic spectroscopy of the van der Waals species KrNO, XeNO, and CH4NO has been investigated via mass-resolved multiphoton ionization (MPI) spectroscopy. Spectra are presented for the two-photon excited electronic transition of the various complexes associated with the C 2Π (v=0) state of nitric oxide. Dissociation pathways are analyzed for XeNO, which appears at the Xe+ mass following MPI. Trends in bonding and spectroscopic constants are discussed.Keywords
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