Anomalous Dielectric Dispersion in Polar Macromolecular Solutions
- 1 October 1955
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 23 (10), 1743-1749
- https://doi.org/10.1063/1.1740573
Abstract
The Kirkwood and Fuoss theory of dielectric dispersion in polymer solutions is recalculated by including the Oseen hydrodynamic interactions in the polymer's diffusion tensor. The theoretical results agree with experiment where comparison is possible. The recalculation gives root‐mean‐square molecular dimensions consistent with values calculated from viscosity and light scattering.Keywords
This publication has 7 references indexed in Scilit:
- The general theory of irreversible processes in solutions of macromoleculesJournal of Polymer Science, 1954
- Electric Moments of Polar Polymers in Relation to Their StructureThe Journal of Chemical Physics, 1951
- DIELECTRIC DISPERSION STUDIES OF POLYVINYL ACETATE IN TOLUENECanadian Journal of Research, 1950
- The Configuration of Real Polymer ChainsThe Journal of Chemical Physics, 1949
- The Intrinsic Viscosities and Diffusion Constants of Flexible Macromolecules in SolutionThe Journal of Chemical Physics, 1948
- Anomalous Dispersion and Dielectric Loss in Polar PolymersThe Journal of Chemical Physics, 1941
- Electrical Properties of Solids. VIII. Dipole Moments in Polyvinyl Chloride-Diphenyl Systems*Journal of the American Chemical Society, 1941