Product kinetic energies, correlations, and scattering anisotropy in the bimolecular reaction O(1D)+H2O→2OH
- 15 October 1992
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 97 (8), 5919-5922
- https://doi.org/10.1063/1.463753
Abstract
Doppler spectroscopy of the 16OH and 18OH products of the 16O(1D)+H218O reaction reveals marked c.m. reactive scattering anisotropy: 16OH scatters in the hemisphere containing the 16O‐atom velocity vector. Internal energies of geminate OH fragments are correlated: fragments of high internal energy form with cofragments of low internal energy.Keywords
This publication has 14 references indexed in Scilit:
- Nascent product states in the photoinitiated reaction of O3 and H2OThe Journal of Chemical Physics, 1992
- Nascent product population distribution in the reaction 16O(1D2)+H218O→16OH+18OHThe Journal of Chemical Physics, 1992
- Full characterization of OH product energetics in the reaction of O(1D2) with hydrocarbonsThe Journal of Chemical Physics, 1991
- The effect of reagent electronic energy on the dynamics of chemical reactions: A high-resolution crossed beam study of O(3P,1D)+H2SThe Journal of Chemical Physics, 1991
- Fragment energy and vector correlations in the overtone-pumped dissociation of HN3 X̃ 1A′The Journal of Chemical Physics, 1991
- Trajectory studies of OH vibrational excitation propensities in the reaction of O(1D) with H2The Journal of Chemical Physics, 1990
- Vector correlations from doppler–broadened lineshapes. State-selected dissociation of methyl nitriteJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1989
- Dynamics of H2O2 photodissociation: OH product state and momentum distribution characterized by sub-Doppler and polarization spectroscopyThe Journal of Chemical Physics, 1986
- Energy partitioning in the reaction 16O(1D)+H2 18O→16OH+18OH. IV. Microscopic probabilities for 16OH+18OH coincident pairsThe Journal of Chemical Physics, 1981
- Rotational and vibrational energy distributions of 16OH(X 2Π) and 18OH(X 2Π) produced in the reaction of O(1D) with H2O and H2 18OThe Journal of Chemical Physics, 1981