Kinetics of Coagulation with Fragmentation: Scaling Behavior and Fluctuations
- 11 August 1986
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 57 (6), 727-730
- https://doi.org/10.1103/physrevlett.57.727
Abstract
The standard coagulation process is generalized to include the effects of fragmentation and a scaling description for the cluster size distribution is developed. The Smoluchowski rate equation is used to calculate the critical exponents describing the steady-state size distribution. Predictions of the scaling and the rate equation are tested by numerical simulations. The mean-field rate-equation results are found to be valid in implying that the upper critical dimension is less than 1.
This publication has 13 references indexed in Scilit:
- The kinetics of cluster fragmentation and depolymerisationJournal of Physics A: General Physics, 1985
- Scaling in steady-state cluster-cluster aggregationPhysical Review A, 1985
- Cluster size distributions in equilibriumZeitschrift für Physik B Condensed Matter, 1984
- Kinetics of reversible polymerizationJournal of Statistical Physics, 1984
- Fluctuation effects in Smoluchowski reaction kineticsPhysical Review A, 1984
- Dynamic Scaling for Aggregation of ClustersPhysical Review Letters, 1984
- Formation of Fractal Clusters and Networks by Irreversible Diffusion-Limited AggregationPhysical Review Letters, 1983
- Equilibrium and kinetic theory of polymerization and the sol-gel transitionThe Journal of Physical Chemistry, 1982
- Coagulation with fragmentationJournal of Physics A: General Physics, 1981
- Note on the Kinetics of Systems Manifesting Simultaneous Polymerization-Depolymerization PhenomenaThe Journal of Physical Chemistry, 1945