The Representation of Gas Properties in Terms of Molecular Clusters
- 1 February 1953
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 21 (2), 236-241
- https://doi.org/10.1063/1.1698866
Abstract
The equation of state of a gas in virial form is derived from the equilibrium constants for the formation of molecular clusters. It is indicated that by choosing effective Lennard‐Jones parameters independently for clusters of various numbers of molecules, the actual virial coefficients may be represented more satisfactorily. Results for the third virial coefficient are shown for A, N2, CO, CO2, CH4, C2H4, CF4, and Xe.Keywords
This publication has 7 references indexed in Scilit:
- The Compressibility of Gaseous Xenon. II. The Virial Coefficients and Potential Parameters of XenonThe Journal of Chemical Physics, 1951
- The Compressibility of Gaseous Xenon. I. An Equation of State for Xenon and the Weight of a Liter of XenonThe Journal of Chemical Physics, 1951
- Thermodynamical properties of nitrogen as functions of density and temperature between −125° and +150°C and densities up to 760 AmagatPhysica, 1951
- Intermolecular Potentials. I. Carbon Tetrafluoride and Sulfur Hexafluoride. II. Carbon DioxideThe Journal of Chemical Physics, 1951
- Compressibility of Gases at Pressures up to 50 Atmospheres. V. Carbon Tetrafluoride in the Temperature Range 0°—400°C. VI. Sulfur Hexafluoride in the Temperature Range 0°—250°CThe Journal of Chemical Physics, 1951
- The Third Virial Coefficient for Non-Polar GasesThe Journal of Chemical Physics, 1950
- On the theory of condensationPhysica, 1938