Thermokinetic Oscillations in Acetaldehyde CSTR Combustion
- 1 May 1993
- journal article
- research article
- Published by Taylor & Francis in Combustion Science and Technology
- Vol. 91 (1-3), 119-142
- https://doi.org/10.1080/00102209308907636
Abstract
Acetaldehyde combustion process in CSTR has been simulated by means of a model capable of describing the complex dynamic behavior experimentally observed, including periodic cool flames, single and complex waveform periodic ignitions and jumps. Critical discussion of models already existing in literature provided the basis for the development of work. Rigorous description of CSTR operation with all parametric dependencies has been implemented and a revised literature kinetic scheme has been adopted. Thermokinetic switches operating in the system evolution are elucidated from the analysis of simulated non-isothermal events.Keywords
This publication has 14 references indexed in Scilit:
- Computer modeling of cool flames and ignition of acetaldehydeCombustion and Flame, 1990
- Numerical studies of a thermokinetic model for oscillatory cool flame and complex ignition phenomena in ethanal oxidation under well-stirred flowing conditionsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1989
- The development and experimental validation of a mathematical model for predicting hot-surface autoignition hazards using complex chemistryCombustion and Flame, 1988
- Thermokinetic interactions: Fundamentals of spontaneous ignition and cool flamesProgress in Energy and Combustion Science, 1987
- Cool flamesProgress in Energy and Combustion Science, 1987
- The heat release rates and cool flames of acetaldehyde oxidation in a continuously stirred tank reactorCombustion and Flame, 1984
- Novel, multiple-stage ignitions in the spontaneous combustion of acetaldehydeCombustion and Flame, 1981
- Oscillatory ignitions and cool flames accompanying the non-isothermal oxidation of acetaldehyde in a well stirred, flow reactorProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1981
- Low temperature oxidation in a stirred flow reactor—II. Acetaldehyde (theory)Combustion and Flame, 1976
- A mathematical model of the cool-flame oxidation of acetaldehydeProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1971