Catalytic, Highly Enantio, and Diastereoselective Nitroso Diels−Alder Reaction
- 12 March 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (13), 4128-4129
- https://doi.org/10.1021/ja049849w
Abstract
This communication presents studies that nitroso Diels−Alder adduct has been furnished in uniformly high yield and high enantioselectivity using nitrosopyridine as a substrate and copper as a catalyst. The obtained Diels−Alder adduct was easily transformed to corresponding chiral amino alcohols without loss of enantioselectivity.Keywords
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