Electric Polarization of Carboxylic Acids in Dilute Solutions of Nonpolar Solvents I. The Relation of Electric Polarization to the Association of Carboxylic Acids in Hydrocarbon Solvents
- 1 May 1941
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 9 (5), 408-414
- https://doi.org/10.1063/1.1750924
Abstract
The association and polar character of various carboxylic acids have been studied in the solvents benzene and heptane by means of measurements of the electric polarization in very dilute solutions. The data have been analyzed by assuming an equilibrium between dimers and monomers of the acid molecules. A rather large anomalous contribution to the polarization of the dimer has been found. Possible origins of this polarization have been briefly considered.Keywords
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