Crystal Structure of Manganese (II) and Cobalt (II) Bromide Dihydrate
- 15 July 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 47 (2), 417-420
- https://doi.org/10.1063/1.1711911
Abstract
The crystal structures at 298°K of MnBr2·2H2O and CoBr2·2H2O have been refined by full‐matrix least‐squares methods using three‐dimensional MoKα intensity data. In these compounds, polymeric chains of metal and bromine atoms arranged in a near‐square planar arrangement with each bromine atom shared by two metal atoms parallel the c axis. The water molecules which fill the remaining octahedral positions about the metal atom provide hydrogen bonds to link adjacent chains.Keywords
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