Thermodynamic and Spectroscopic Study of Vinylidene Chloride. II. Vibrational Spectra

Abstract

The Raman spectra of vinylidene chloride liquid excited by the 5461‐A line and the 4358‐A group of lines of the mercury arc have been recorded photoelectrically and some depolarization measurements have been made. The infrared spectrum of the vapor in the 700–320 cm^—1 region has also been recorded. These data have enabled some uncertainties in the published vibrational assignment to be resolved but they do not indicate the need for major changes in this assignment.