THE PARTIAL REDUCTION OF CARBOXYLIC ACIDS TO ALDEHYDES via 3-ACYLTHIAZOLIDINE-2-THIONES WITH DIISOBUTYLALUMINUM HYDRIDE
- 5 December 1977
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 6 (12), 1443-1446
- https://doi.org/10.1246/cl.1977.1443
Abstract
3-Acylthiazolidine-2-thiones (1), prepared from free carboxylic acids and thiazolidine-2-thione by using 2-chloro-1-methylpyridinium iodide in the presence of triethylamine, were reduced to the aldehydes with diisobutylaluminum hydride (DIBAH) in good yields even when excess amount of DIBAH was used.Keywords
This publication has 2 references indexed in Scilit:
- New Method for the Preparation of Carboxylic EstersBulletin of the Chemical Society of Japan, 1977
- Selective Reductions. V. The Partial Reduction of Tertiary Amides by Lithium Di- and Triethoxyaluminohydrides-A New Aldehyde Synthesis via the DimethylamidesJournal of the American Chemical Society, 1964