Strong exciton-erbium coupling in Si nanocrystal-doped SiO2

Abstract

Silicon nanocrystals were formed in SiO 2 using Si ion implantation followed by thermal annealing. The nanocrystal-doped SiO 2 layer was implanted with Er to a peak concentration of 1.8 at. %. Upon 458 nm excitation the sample shows a broad nanocrystal-related luminescence spectrum centered around 750 nm and two sharp Er luminescence lines at 982 and 1536 nm. By measuring the excitation spectra of these features as well as the temperature-dependent intensities and luminescence dynamics we conclude that (a) the Er is excited by excitons recombining within Si nanocrystals through a strong coupling mechanism, (b) the Er excitation process at room temperature occurs at a submicrosecond time scale, (c) excitons excite Er with an efficiency >55%, and (d) each nanocrystal can have at most ∼1 excited Er ion in its vicinity.