Critical Analysis of Heat—Capacity Data and Evaluation of Thermodynamic Properties of Ruthenium, Rhodium, Palladium, Iridium, and Platinum from 0 to 300K. A Survey of the Literature Data on Osmium.

Abstract

The literature sources of heat‐capacity data on ruthenium, rhodium, palladium, osmium, iridium, and platinum have been compiled and the data critically analyzed. Except for osmium where data are lacking, best values of thermodynamic properties have been evaluated between 0 and 300 K from the analyses. The literature values of heat capacity, the electronic coefficient of heat capacity (γ), and the zero K limiting Debye characteristic temperature (θ_D(0)) are compared. The sources of data are tabulated chronologically along with the temperature range of measurements, purity of sample, and the pertinent experimental procedures used. A bibliography of the references is listed.