Relaxation Term of the Limiting Law of the Conductance of Electrolyte Mixtures
- 15 January 1965
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 42 (2), 462-469
- https://doi.org/10.1063/1.1695956
Abstract
The calculation of the limiting‐law terms from the cluster theory of conductance, as presented in recent papers, is extended to solutions of mixtures of electrolytes. The more general evaluation of one of the cluster integrals required for this purpose is achieved by using some results from the theory of symmetric polynomials. The resulting relaxation term is very different in form from that of Onsager and Kim but, at least for solutions of three solute species, the two theories give the same numerical results for the ionic conductances in a variety of systems.Keywords
This publication has 6 references indexed in Scilit:
- On the Electrophoretic Term of the Limiting Law for Electrical Conductance in SolutionsThe Journal of Chemical Physics, 1965
- On the limiting law for electrical conductance in ionic solutionsPhysica, 1964
- A cluster expansion for the electrical conductance of solutionsPhysica, 1964
- Equivalent and Ionic Conductances for Mixtures of Potassium and Lithium Chlorides in Aqueous Solution at 25°Journal of the American Chemical Society, 1959
- The Relaxation Effects in Mixed Strong ElectrolytesThe Journal of Physical Chemistry, 1957
- Irreversible Processes in Electrolytes. Diffusion, Conductance and Viscous Flow in Arbitrary Mixtures of Strong ElectrolytesThe Journal of Physical Chemistry, 1932