Structured emission of tetrahedral complexes due to Jahn-Teller and pseudo-Jahn-Teller effects
- 22 August 2001
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 64 (10), 104302
- https://doi.org/10.1103/physrevb.64.104302
Abstract
Tetrahedral complexes with an excited state consisting of two closely lying triplet states are considered. The full interaction Hamiltonian, including ligand field, Jahn-Teller, pseudo-Jahn-Teller, and spin-orbit interactions is constructed. The emission-band shape is numerically calculated within the semiclassical approach using Monte Carlo integration. The results of this numerical analysis are applied to the system. Comparison with experimentally obtained spectra shows that this theory explains the observed triple-peak structure.
Keywords
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