Palladium-catalyzed addition of disulfides and diselenides to alkynes under solvent free conditionsElectronic supplementary information (ESI) available: full experimental details of synthetic procedure, compound separation and purification, details of spectroscopic studies, kinetic measurements and compound characterization. See http://www.rsc.org/suppdata/ob/b3/b312471a/

Abstract

An efficient methodology was developed for performing palladium-catalyzed E–E (E = S, Se) bond addition to alkynes under solvent free conditions. Compared to reaction in solvent significant enhancement of reaction rate, improved efficiency and remarkable catalyst stability were observed under solvent free conditions. The addition reactions were carried out with high stereoselectivity and yields in a short reaction time.