Reactions of Iodinated Vinylidene Complexes Generated from 1-Iodo-1-alkynes and W(CO)5(thf)
- 1 January 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 124 (4), 518-519
- https://doi.org/10.1021/ja0113091
Abstract
We have succeeded in generating iodinated tungsten vinylidene complexes from 1-iodo-1-alkynes and W(CO)5(thf), and have employed these complexes for two types of synthetically useful reactions, that is, 6π-electrocyclization for o-(iodoethynyl)styrenes and endo-selective cyclization for ω-iodoacetylenic silyl enol ethers.Keywords
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