Optical Resolution of Chirally Functionalized [60]Fullerene Through Formation of Diastereomeric Methoxyphenylacetic Acid Esters
- 1 July 1999
- journal article
- research article
- Published by Taylor & Francis in Fullerene Science and Technology
- Vol. 7 (4), 519-528
- https://doi.org/10.1080/10641229909351358
Abstract
Optical resolution of chirally functionalized [60]fullerene has been achieved through formation of diastereomeric α-methoxyphenylacetic acid (MPA) esters. The diastereomeric ester products were easily separated either by open column silica gel chromatography or by high pressure liquid chromatography (HPLC) with BuckyPrep® column.Keywords
This publication has 11 references indexed in Scilit:
- Resolution and absolute configuration of a C2-symmetric trans-2, 5-disubstituted fulleropyrrolidineTetrahedron Letters, 1998
- Absolute configuration of chiral fullerenes and covalent derivatives from their calculated circular dichroism spectraJournal of the Chemical Society, Perkin Transactions 2, 1998
- Synthetic and Computational Studies on Symmetry-Defined Double Cycloaddition of a New Tris-Annulating Reagent to C60The Journal of Organic Chemistry, 1997
- Configurational Description of Chiral Fullerenes and Fullerene Derivatives with a Chiral Functionalization PatternHelvetica Chimica Acta, 1997
- Biological Activity of Water-Soluble Fullerenes. Structural Dependence of DNA Cleavage, Cytotoxicity, and Enzyme Inhibitory Activities Including HIV-Protease InhibitionBulletin of the Chemical Society of Japan, 1996
- Tertiary phosphines, P-chiral phosphinites and phosphonic acid esters bearing fullerene substituent. Metal complexes and redox propertiesTetrahedron, 1996
- MTPA vs MPA in the Determination of the Absolute Configuration of Chiral Alcohols by 1H NMRThe Journal of Organic Chemistry, 1996
- Regio- and diastereo-controlled double cycloaddition to [60] fullerene: one-step synthesis of Cs and C2 chiral organofullerenes with new tris-annulating reagentsChemical Communications, 1996
- Langmuir-Blodgett Film of Amphiphilic C60 Carboxylic AcidLangmuir, 1995
- [1 + 2] and [3 + 2] cycloaddition reactions of vinylcarbenes with C60Tetrahedron Letters, 1993