SOME PALLADIUM(II) COMPLEXES OF 1,2-BIS(MERCAPTO)ORTHOCARBORANE
- 1 April 1986
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 14 (4), 309-313
- https://doi.org/10.1080/00958978608075848
Abstract
Coordination compounds of the type Pd(DMC)L and [Pd(DMC)2]C where DMC is 1,2-bis(mercapto)-o- carborane, L = 1-diphenylphosphino-o-carborane (HPC), 1,2-bis(diphenylphosphino-o-carborane (NPC) and C [dbnd] H+ or tetraethylammonium cation, have been prepared and characterized by IR, Raman and electronic spectroscopy, magnetic and conductivity measurements. DMC behaves as a bidentate sulphur donor ligand and the tertiary phosphine (HPC) and ditertiary phosphines (DPC and NPC) are bonded through the phosphorous atoms to produce a planar PdS2P2 skeleton of C2v symmetry.Keywords
This publication has 9 references indexed in Scilit:
- Some nickel(II) complexes of tertiary phosphines containing o-carborane as backboneInorganica Chimica Acta, 1984
- Complexes of metal ions with phosphorus or arsenic containing ligands : XVII. Photochemically induced substitution in group VI metal carbonyls with ditertiary phosphines and arsinesJournal of Organometallic Chemistry, 1974
- Vibrational spectra of some gold(I), palladium(II), and platinum(II) complexes with trialkylphosphines and trialkylarsinesJ. Chem. Soc. A, 1970
- Preparation and vibrational spectra of square-planar palladium(II) complexes of the type trans-PdX2(SR2)2J. Chem. Soc. A, 1970
- 1,2-Bis-substituted o-carborane complexes. II. Nickel(II) and cobalt(II) complexes derived from the ligand 1,2-bis(mercapto)-o-carboraneInorganic Chemistry, 1967
- The skeletal stretching frequencies of some bridged platinum and palladium chloro-complexesJ. Chem. Soc. A, 1967
- Coordination Compounds with Delocalized Ground States. Bisdithioglyoxalnickel and Related Complexes1a,bJournal of the American Chemical Society, 1965
- The Electronic Structures of Square-Planar Metal Complexes. II. The Complexes of Maleonitriledithiolate with Copper(II), Nickel(II), Palladium(II), and Platinum(II)Inorganic Chemistry, 1964
- The Reactions of Nickel(II) with 2,3-Dimercapto-1-propanol1Journal of the American Chemical Society, 1959