The Effect of Pressure on Self-Diffusion in Carbon Disulfide
- 1 February 1953
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 21 (2), 267-273
- https://doi.org/10.1063/1.1698872
Abstract
A method has been developed for measuring diffusion coefficients in liquids to 10 000 atmospheres pressure. Measurements have been made over this pressure range at 0°, 20°, and 40°C for the system CS2–CSS35. The results are interpreted in terms of the enthalpy, entropy, and volume of activation as a function of temperature and pressure.Keywords
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